Hierarchical Core–Shell Structure of ZnO Nanorod@NiO/MoO<sub>2</sub> Composite Nanosheet Arrays for High-Performance Supercapacitors
- Publication date
- Publisher
Abstract
A hierarchical
core–shell structure of ZnO nanorod@NiO/MoO<sub>2</sub> composite
nanosheet arrays on nickel foam substrate for high-performance
supercapacitors was constructed by a two-step solution-based method
involving two hydrothermal processes followed by a calcination treatment.
Compared to one composed of pure NiO/MoO<sub>2</sub> composite nanosheets,
the hierarchical core–shell structure electrode displays better
pseudocapacitive behaviors in 2 M KOH, including high areal specific
capacitance values of 1.18 F cm<sup>–2</sup> at 5 mA cm<sup>–2</sup> and 0.6 F cm<sup>–2</sup> at 30 mA cm<sup>–2</sup> as well as relatively good rate capability at high
current densities. Furthermore, it also shows remarkable cycle stability,
remaining at 91.7% of the initial value even after 4000 cycles at
a current density of 10 mA cm<sup>–2</sup>. The enhanced pseudocapacitive
behaviors are mainly due to the unique hierarchical core–shell
structure and the synergistic effect of combining ZnO nanorod arrays
and NiO/MoO<sub>2</sub> composite nanosheets. This novel hierarchical
core–shell structure shows promise for use in next-generation
supercapacitors