Partial
Hydrogenation of a Tetranuclear Titanium Nitrido
Complex with Ammonia Borane
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Abstract
The treatment of [{Ti(η<sup>5</sup>-C<sub>5</sub>Me<sub>5</sub>)}<sub>4</sub>(μ<sub>3</sub>-N)<sub>4</sub>] with NH<sub>3</sub>BH<sub>3</sub> leads to the paramagnetic
imidonitrido complex [{Ti(η<sup>5</sup>-C<sub>5</sub>Me<sub>5</sub>)}<sub>4</sub>(μ<sub>3</sub>-N)<sub>3</sub>(μ<sub>3</sub>-NH)], which can also be obtained by stepwise proton and electron
transfer with HOTf and [K(C<sub>5</sub>Me<sub>5</sub>)]
