Positive
Magneto-LC Effect in Conjugated Spin-Bearing
Hexabenzocoronene
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Abstract
The
first neutral spin carrying hexabenzocoronene (HBC) derivative
is described. The conjugated phenyl nitroxide substituted HBC with
five alkyl chains exhibits a positive magneto-LC effect in columnar
hexagonal liquid crystalline phase as probed by differential scanning
calorimetry and electron paramagnetic resonance spectroscopy. Surprisingly,
at 140 K the Δ<i>M</i><sub>S</sub> = 2 transition
can be observed indicating a thermally accessible triplet state between
the neighboring molecules in the columnar arrangements