Optimizing the Design and Synthesis of Supported Silver Nanoparticles for Low Cost Water Disinfection

Abstract

Silver nanoparticles (AgNPs) were successfully synthesized and impregnated on silica using chemical reduction methods. XPS and Ag <i>K</i>-edge XANES analysis revealed that the impregnation of AgNPs onto silica using a chitosan + sodium borohydride (NaBH₄) method results in higher silver loading and Ag(0)/Ag­(I) ratio compared to that obtained using NH₃ + NaBH₄/glucose methods. The effects of the dosage of chitosan on silver loading, Ag­(I) release, and bactericidal activities of AgNP-impregnated silica were investigated, with results showing that, at high dosages of chitosan, Ag­(I) released from AgNP-impregnated silica plays an important role in disinfection, while AgNP-mediated bactericidal action dominates at low dosages of chitosan. To further decrease the manufacturing cost, partially oxidized “black rice husk ash” containing substantial residual carbon was applied as AgNP support and found to lead to a greater degree of silver impregnation and to exhibit a longer disinfection lifetime than that of lower carbon content silica supports. On the basis of these findings, it is clear that considerable scope exists for careful optimization in the design and production of AgNP-based bactericidal materials for water treatment purposes