<div><p>A new and an efficient synthesis of 4-imino-3-(arylidene)-azetidine-2-thiones is reported. The reaction of arylidenemalononitriles with phosphorus pentasulfide and ethanol affords the title products in good yields. Elemental analysis, infrared, <sup>1</sup>H NMR, <sup>13</sup>C NMR and mass spectral data elucidated structure of newly synthesized compounds.</p></div