Hierarchical Ordering in Ternary Co-Crystals of C₆₀, <i>N</i>‑Benzyl Ammonium Resorcinarene Bromide and Solvent Molecules

Abstract

Co-crystallization of C₆₀ together with an <i>N</i>-benzyl ammonium resorcinarene bromide from toluene:1,2-dichloroethane mixture results in ternary co-crystals where the modulated C₆₀ lattice entraps dimeric resorcinarene assemblies, which, in turn, have 149 and 280 ų cavities filled with 1,2-dichloroethane molecules