Phosphorescent
Iridium(III) Complexes of Cyclometalated
5‑Aryl‑1<i>H</i>‑1,2,4-Triazole Ligands:
Structural, Computational, Spectroscopic, and Device Studies
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Abstract
Ir(III)
complexes of cyclometalated 5-aryl-1<i>H</i>-1,2,4-triazole
ligands are highly efficient, phosphorescent emitters. We describe
herein a series of <i>fac</i>-IrL<sub>3</sub> complexes,
in which the nature of aryl substituents are shown to strongly affect
emission wavelength over the range 453–499 nm. Computational
and structural studies indicate that for aryl groups the point of
attachment and dihedral angle with respect to the cyclometalated ring
influence emission color. Significantly, this degree of color tuning
may be achieved without resorting to electron-withdrawing or -donating
groups. Photo- and electroluminescence device studies of the different
emitters indicate that they are generally highly efficient: photoluminescent
efficiencies >90% and external quantum efficiencies of up to 22%
are
observed