Synthesis and Characterization
of Polysulfone-Containing
Poly(butylene terephthalate) Segmented Block Copolymers
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Abstract
A facile synthetic approach to segmented
polysulfone-containing
polyesters affords a versatile family of high-temperature thermoplastics
with tunable thermomechanical properties. End-capping of phenol-terminated
polysulfone (PSU) using ethylene carbonate generated telechelic oligomers
with primary alcoholic functionality. Melt transesterification of
dimethyl terephthalate and 1,4-butanediol in the presence of PSU oligomers
yielded high molecular weight segmented block copolymers with alternating
PSU and poly(butylene terephthalate) (PBT) sequences. Systematic variation
in PSU incorporation resulted in tunable PBT segment length and accompanying
thermal properties. DSC and SAXS elucidated a miscible, amorphous
PSU and PBT phase, and PBT crystallinity remained below an 80 wt %
incorporation of PSU. Dynamic mechanical analysis (DMA) revealed a
crystallinity-dependent plateau regime above the copolymers glass
transition temperature (<i>T</i><sub>g</sub>), while SAXS
and WAXD confirmed a semicrystalline morphology below 80 wt % PSU.
Incorporation of PSU segments significantly affected the crystallization
and thermomechanical properties of PBT, and as a result these copolymers
offer impact as chemically resistant, high-temperature thermoplastics
due to their crystallinity, thermal stability, and high-temperature
operating window