Modular and Highly Stereoselective Approach to All-Carbon
Tetrasubstituted Alkenes
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Abstract
A modular and completely stereoselective
approach for the construction
of all-carbon tetrasubstituted alkenes is described. It is based on
the three-fold, sequential metal-catalyzed, cross-coupling functionalization
of simple enolphosphate dibromide templates with carbon nucleophiles,
affording tetrasubstituted alkenes as single isomers