Zadaním práce je návrh rezidencie pre diplomatické účely. Stavba sa nachádza v lokalite Troja, ktorá bola spracovaná v súčasne v ateliéri.The assignment was to design a residence with diplomatic purpose. Building is located in Troja, which was elaborated in studio

Luca Bellarosa (1364124)

Max García-Melchor (1642873)

Núria López (1325190)

Mochnacký Daniel

Digital Library of the Czech Technical University in Prague

Diplomatic Villa

Despite
its ubiquity in homogeneous and enzymatic catalysis, concerted
mechanisms have been overlooked for heterogeneously catalyzed reactions.
The elusive nature of transition states leaves Density Functional
Theory, DFT, as the only robust tool for their identification and
characterization. By means of this method, we show that a concerted
path takes part in the recently discovered semihydrogenation of propyne
on CeO2, for which an excellent activity and selectivity
have been reported. The high surface H coverage imposed by the experimental
hydrogenation conditions induces site isolation and drives the reaction
through a six-membered ring transition state. This unprecedented pathway
accounts for many of the experimental observations, such as the unique syn-stereoselectivity, the excellent alkene selectivities,
or the high temperature and large H2/alkyne ratios required

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Unique Reaction Path in Heterogeneous Catalysis: The
Concerted Semi-Hydrogenation of Propyne to Propene on CeO2

https://figshare.com/articles/Unique_Reaction_Path_in_Heterogeneous_Catalysis_The_Concerted_Semi_Hydrogenation_of_Propyne_to_Propene_on_CeO_sub_2_sub_/2237461

Diplomatic Villa

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Digital Library of the Czech Technical University in Prague

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