Engineering
a Water-Dispersible, Conducting, Photoreduced
Graphene Oxide
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Abstract
A critical limitation that has hampered
widespread application
of the electrically conducting reduced graphene oxide (<i>r</i>-GO) is its poor aqueous dispersibility. Here we outline a strategy
to obtain water-dispersible conducting <i>r</i>-GO sheets,
free of any stabilizing agents, by exploiting the fact that the kinetics
of the photoreduction of the insulating GO is heterogeneous. We show
that by controlling UV exposure times and pH, we can obtain <i>r</i>-GO sheets with the conducting sp<sup>2</sup>-graphitic
domains restored but with the more acidic carboxylic groups, responsible
for aqueous dispersibility, intact. The resultant photoreduced <i>r</i>-GO sheets are both conducting and water-dispersible