Gas-Phase
Reactions of CF<sup>+</sup> with Molecules
of Interstellar Relevance
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Abstract
We have studied the gas-phase reactions
of CF<sup>+</sup> with
24 neutral species. Reaction rate constants and product branching
fractions are measured at 298 K using a flowing afterglow-selected
ion flow tube. Experimental work is supported by computational chemistry
calculations to provide insight into the reactivity of classes of
neutral molecules. Reactions of CF<sup>+</sup> with small triatomic
species and oxygen-containing organic molecules produce the stable
molecule CO. The product branching fractions are discussed, and the
potential energy surfaces for a few representative reactions are examined.
CF<sup>+</sup> is highly reactive with complex molecules and will
likely be destroyed in dense environments in the interstellar medium.
However, the lack of reactivity with small diatomic molecules will
likely enable its survival in diffuse regions