Emulsions Stabilized by Silica Rods via Arrested Demixing
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Abstract
A binary
liquid–liquid mixture with a lower critical solution
temperature (LCST) when heated above a critical temperature undergoes
demixing. During the initial phase of demixing process, high-energy
liquid–liquid interfaces are created before both liquids eventually
phase separate. By incorporating well-characterized colloidal silica
rods in a homogeneous one-phase liquid–liquid mixture of lutidine/water
(L/W) before inducing phase separation, we show that colloidal rod
stabilized Pickering emulsions can be obtained. We show that the droplet
size of Pickering emulsions can be tuned by varying particle concentration,
and the droplet size distribution follows the prediction of the limited
coalescence model