Asymmetric Supercapacitive Characteristics of PANI
Embedded Holey Graphene Nanoribbons
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Abstract
In
the present study, graphene oxide nanoribbons (GONR) and reduced
graphene oxide nanoribbons (RGONR) supported polyaniline (PANI) nanocomposites
are synthesized via an <i>in situ</i> chemical polymerization
method and investigated for supercapacitor electrodes. Electrochemical
studies performed by cyclic voltammetry and galvanostatic charge–discharge
(GCD) measurements suggest that both nanocomposites possess enhanced
specific capacitance (<i>C</i><sub>sp</sub> as 740 F/g for
GONR/PANI and 1180 F/g for RGONR/PANI at 5 mV/s). GONR/PANI and RGONR/PANI
nanocomposites show good rate capability with high <i>C</i><sub>sp</sub> upon increasing the current density from 2 to 20 A/g
in GCD measurements, approximately 55% decay in <i>C</i><sub>sp</sub> value of the nanocomposites is observed compared to
pristine PANI (∼70%). The undertaken study signifies enhanced
electrical and electrochemical properties of GONR/RGONR supported
PANI nanocomposites due to a synergistic effect of GONR/RGONR and
PANI. Furthermore, asymmetric devices are fabricated using GONR/RGONR
as the negative electrode, while GONR/PANI and RGONR/PANI are used
as the positive electrode, which exhibit significant enhancement in
energy density and device performance