Atomic Structural Studies on Thin Single-Crystalline
Misfit-Layered Nanotubes of TbS-CrS<sub>2</sub>
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Abstract
Various nanotubes
from ternary misfit compounds have been reported
in recent years. In the present work, the detailed atomic structure
and chemical configuration of misfit-layered nanotubes based on the
TbS-CrS<sub>2</sub> are reported. These analyses have been developed
via different transmission electron microscopy techniques, including
high-resolution scanning transmission electron microscopy, electron
diffraction, and electron energy loss spectroscopy. These structural
analyses show that two different kinds of nanotubes can be produced:
a “regular” nanotube and a “wavy” one.
Both kinds of nanotubes show the alternating arrangements of the TbS
and CrS<sub>2</sub> subsystems; however, the wavy ones present a nearly
periodically deficiency in terbium. In addition to the structural
investigation, the chemical analyses have proved that the outer layer
of both kinds of nanotubes is composed of the elements Cr and S. All
these findings helped to understand the growth mechanism during the
sulfurization reaction taking place in the synthesis process