Liquid Phase Exfoliation of Two-Dimensional Materials
by Directly Probing and Matching Surface Tension Components
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Abstract
Exfoliation of two-dimensional (2D)
materials into mono- or few layers is of significance for both fundamental
studies and potential applications. In this report, for the first
time surface tension components were directly probed and matched to
predict solvents with effective liquid phase exfoliation (LPE) capability
for 2D materials such as graphene, h-BN, WS<sub>2</sub>, MoS<sub>2</sub>, MoSe<sub>2</sub>, Bi<sub>2</sub>Se<sub>3</sub>, TaS<sub>2</sub>, and SnS<sub>2</sub>. Exfoliation efficiency is enhanced when the
ratios of the surface tension components of the applied solvent is
close to that of the 2D material in question. We enlarged the library
of low-toxic and common solvents for LPE. Our study provides distinctive
insight into LPE and has pioneered a rational strategy for LPE of
2D materials with high yield