A New
Crystal Structure of Au<sub>36</sub> with a
Au<sub>14</sub> Kernel Cocapped by Thiolate and Chloride
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Abstract
This
study presents a new crystal structure of a gold nanocluster
coprotected by thiolate and chloride, with the formula of Au<sub>36</sub>(SCH<sub>2</sub>Ph-<sup>t</sup>Bu)<sub>8</sub>Cl<sub>20</sub>. This
nanocluster is composed of a Au<sub>14</sub> core with two Cl atoms,
a pair of pentameric Au<sub>5</sub>(SCl<sub>5</sub>) staple motifs,
and a pair of hexameric Au<sub>6</sub>(S<sub>3</sub>Cl<sub>4</sub>) motifs. It is noteworthy that the “Au–Cl–Au”
staple motifs are observed for the first time in thiolate protected
gold nanoclusters. More importantly, the formation of the Cl–Au<sub>3</sub> motifs is found to be mainly responsible for the configuration
of the gold nanocluster. This work will offer a new perspective to
understand how the ligands affect the crystal structure of gold nanocluster