Controllable Synthesis
of Covalent Porphyrinic Cages
with Varying Sizes via Template-Directed Imine Condensation Reactions
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Abstract
Covalent
porphyrinic cages (CPCs) have been a target of interest
for years. In this paper, we report the design and synthesis of two
CPCs in which the cofacial porphyrins have a distance of 7.66 and
11.96 Å via template-directed imine condensation reactions and
through the selective choice of templating linker and diamine length