Cui, Chunming

English

In this dissertation, bulky multidentate ligands            1-aza-allyl, N-functionized aryl, diketiminato were            used for the preparation of novel aluminum compounds in            all oxidation states. The reactivity of base stabilized            aluminum hydrides towards chalcogens were investigated.            The reduction of diketiminato aluminum dihalide with            potassium afforded the first instance of a carbene            analogue of aluminum, whereas similar reduction in the            presence of alkynes generated cyclopropene analogues of            aluminum. The reactions and structures of these unique            species were presented

Georg-August-University Göttingen

Aluminum (I, II, III) Compounds with Multidentate Ligands: Syntheses, Reactivity, and Structures

https://ediss.uni-goettingen.de/bitstream/11858/00-1735-0000-0006-B0E1-C/1/cui.pdf

Aluminum (I, II, III) Compounds with Multidentate Ligands: Syntheses, Reactivity, and Structures

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Georg-August-University Göttingen