Molecular Structural Basis for Stereocomplex Formation
of Polylactide Enantiomers in Dilute Solution
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Abstract
Poly(l-lactide) (PLLA) and
poly(d-lactide) (PDLA)
alternatively pack with each other and form stereocomplex crystals
(SCs). The crystal habits of SCs formed in the dilute solution highly
depend on the molecular weight (⟨<i>M</i><sub>w</sub>⟩). In this study, we investigated chain-folding (CF) structure
for <sup>13</sup>C labeled PLLA (<i>l</i>-PLLA) chains in
SCs with PDLAs that have either high or low ⟨<i>M</i><sub>w</sub>⟩s by employing an advanced Double Quantum (DQ)
NMR. It was found that the ensemble average of the successive adjacent
re-entry number ⟨<i>n</i>⟩ for the <i>l</i>-PLLA chains drastically change depending on ⟨<i>M</i><sub>w</sub>⟩s of the counter PDLA chains in the
SCs. It was concluded that the CF structures of <i>l</i>-PLLA depending on ⟨<i>M</i><sub>w</sub>⟩s
of PDLA determine the crystal habits of SCs