Polarity-Free Epitaxial
Growth of Heterostructured
ZnO/ZnS Core/Shell Nanobelts
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Abstract
Surface-polarity-induced formation of ZnO/ZnS heterojunctions
has
a common characteristic that ZnS (or ZnO) is exclusively decorated
on a Zn-terminated (0001) surface of ZnO (or ZnS) due to its comparatively
chemically active nature to an O (or S)-terminated (000–1)
surface. Here, we report a polarity-free and symmetrical growth of
ZnS on both ZnO±(0001) surfaces to form a new heterostructured
ZnO/ZnS core/shell nanobelt via a thermal evaporation method. Remarkably,
the ZnS shell is single-crystalline and preserves the structure and
orientation of the inner ZnO nanobelt with an epitaxial relationship
of (0001)<sub>ZnO</sub>//(0001)<sub>ZnS</sub>; [2–1–10]<sub>ZnO</sub>//[2–1–10]<sub>ZnS</sub>. Through this case,
we demonstrate that an anion-terminated polar surface could also drive
the nucleation and growth of nanostructures as the cation-terminated
surface by controlling the growth kinetics. Considering high-performance
devices based on ZnO/ZnS heterojunctions, the current ZnO/ZnS nanobelt
is advantageous for optoelectronic applications due to its single-crystalline
nature and relatively more efficient charge separation along 3D heterointerfaces