An Environmentally Benign Cycle To Regenerate Chitosan
and Capture Carbon Dioxide by Ionic Liquids
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Abstract
A new cycle platform has been built
to provide an efficient method
for biomass utilization and greenhouse gas control simultaneously
via the interplay of interactions between ionic liquids (ILs), chitosan,
and CO<sub>2</sub>. All samples, including chitosan/IL solutions,
chitin/IL solutions, and pure ILs, were employed to perform experiments
on CO<sub>2</sub> capture/release. The results indicated that chitosan
with a high degree of deacetylation can capture CO<sub>2</sub> in
a nearly 2:1 stoichiometry. In the meantime, different mechanisms
of chitosan regeneration from acetate-based ILs and others were explored.
For the acetate-based ILs, <sup>1</sup>H and <sup>13</sup>C NMR spectroscopy
implied the formation of new species of [imida<sup>+</sup>–COO<sup>–</sup>] after the chemical CO<sub>2</sub> capture, while
only the changes of volume expansion and solvatochromic UV–vis
parameters can give rise to chitosan regeneration for the ILs with
less basic anions. In addition, raw chitosan was used to demonstrate
the cycle by selective capture of CO<sub>2</sub> and precipitation
from [Bmim]OAc using compressed CO<sub>2</sub>