Phase Transition of Tetra‑<i>n</i>‑butylammonium
Bromide Hydrates Enclosing Krypton
- Publication date
- Publisher
Abstract
The phase equilibrium conditions
for krypton (Kr)–tetra-<i>n</i>-butylammonium bromide
(TBAB)–water systems were
determined using an isochoric method. The pressure and temperature
ranges were (0.06 to 1.0) MPa and (280 to 290) K, respectively, and
TBAB solutions had TBAB molar fractions, <i>x</i><sub>TBAB</sub>, of 0.0062, 0.0138, 0.0234, and 0.0359. A second order transition
of the TBAB hydrate was observed in all the Kr–TBAB–water
systems. In the region at lower pressure than the phase transition
point, the Kr–TBAB–water systems with low concentration
(<i>x</i><sub>TBAB</sub> = 0.0062 and 0.0138) and high concentration
(<i>x</i><sub>TBAB</sub> = 0.0234 and 0.0359) prefer to
form TBAB·38H<sub>2</sub>O and TBAB·26H<sub>2</sub>O hydrates,
respectively. However, a <i>new</i> TBAB hydrate was observed
as a stable crystal structure in the higher pressure regions. Raman
spectrum of the new TBAB hydrate shows band shapes remarkably similar
to that of <i>pure</i> TBAB·38H<sub>2</sub>O with the
crystalline space group <i>Pmma</i> in the frequency ranges
of the lattice for C–C stretching, C–H bending, the
C–H stretching bands of the −CH<sub>2</sub> groups of
TBA<sup>+</sup> molecules, and the O–H stretching modes of
water molecules, excluding the C–H stretching bands of the
CH<sub>3</sub> groups of TBA<sup>+</sup> molecules