Borate chemistry offers attractive
features for iron based polyanionic
compounds. For battery applications, lithium iron borate has been
proposed as cathode material because it has the lightest polyanionic
framework that offers a high theoretical capacity. Moreover, it shows
promising characteristics with an element combination that is favorable
in terms of sustainability, toxicity, and costs. However, the system
is also associated with a challenging chemistry, which is the major
reason for the slow progress in its further development as a battery
material. The two major challenges in the synthesis of LiFeBO<sub>3</sub> are in obtaining phase purity and high electrochemical activity.
Herein, we report a facile and scalable synthesis strategy for highly
pure and electrochemically active LiFeBO<sub>3</sub> by circumventing
stability issues related to Fe<sup>2+</sup> oxidation state by the
right choice of the precursor and experimental conditions. Additionally,
we carried out a Mössbauer spectroscopic study of electrochemical
charged and charged–discharged LiFeBO<sub>3</sub> and reported
a lithium diffusion coefficient of 5.56 × 10<sup>–14</sup> cm<sup>2</sup> s<sup>–1</sup> for the first time