A zirconium(IV)-based
UiO-topological metal–organic framework (UiO-68Se) containing
benzoselenadiazole was synthesized by an approach of the mixed dicarboxylate
struts, which show highly efficient and recycalable photocatalytic
activity for aerobic cross-dehydrogenative coupling reactions between
tertiary amines and various carbon nucleophiles under visible-light
irradiation
