Dynamic Quantum Molecular Sieving Separation of D<sub>2</sub> from H<sub>2</sub>–D<sub>2</sub> Mixture with Nanoporous Materials

Abstract

Quantum molecular sieving separability of D<sub>2</sub> from an H<sub>2</sub>–D<sub>2</sub> mixture was measured at 77 K for activated carbon fiber, carbon molecular sieve, zeolite and single wall carbon nanotube using a flow method. The amount of adsorbed D<sub>2</sub> was evidently larger than H<sub>2</sub> for all samples. The maximum adsorption ratio difference between D<sub>2</sub> and H<sub>2</sub> was 40% for zeolite (MS13X), yielding a selectivity for D<sub>2</sub> with respect to H<sub>2</sub> of 3.05

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