Redox-Controlled Crotyl
Alcohol Selective Oxidation:
In Situ Oxidation and Reduction Dynamics of Catalytic Pd Nanoparticles
via Synchronous XANES/MS
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Abstract
In-situ, synchronous MS/XANES reveals the Pd catalyzed
selective
aerobic oxidation of crotyl alcohol is regulated by the balance between
the oxidation state and reducibility. Dynamic XANES measurements provide
a new, rapid method to determine redox kinetics of nanoparticles and
identify important parameters to optimize catalyst design