Effect of Co<sup>2+</sup> Substitution in the Framework
of Carbonate Intercalated Cu/Cr LDH on Structural, Electronic, Optical,
and Photocatalytic Properties
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Abstract
In the present work, a series of Cu–Co/Cr ternary
LDHs containing
CO<sub>3</sub><sup>2–</sup> in the interlayer was prepared
by coprecipitation method. To investigate the effect of divalent metal
ions on the catalytic activity, we vaired Cu/Co atomic ratios, keeping
constant the atomic ratio of Cu+Co/Cr (2:1). Several characterization
tools, such as powder X-ray diffraction (PXRD), Brunauer–Emmett–Teller
surface area, Fourier transform infrared spectroscopy, thermogravimetric
analysis, transmission electron microscopy, and UV–vis diffuse
reflectance spectroscopy, were employed to study the phase structures,
textural, and optical properties of the samples. The PXRD of all samples
showed the characteristic pattern of the hydrotalcite without any
detectable impurity phases. The expected cell parameter variation
was calculated assuming the Vegard’s law and proved the ideal
atomic arrangement for the cations in the brucite layer. The shifting
of the diffraction plane “d110” toward lower angle clearly
indicates that Co<sup>2+</sup> is substituted in the brucite layer.
The formation of the highest amount of hydroxyl radicals (OH<sup>•</sup>) on the surface of visible-light illuminated LDHs detected by the
luminescence technique using terephthalic acid as probe molecules
supports the highest activity LDH-4 with Cu/Co atomic ratio 0.033
+ 0.1 (i.e., 1:3) toward MG degradation. The degradation of malachite
green (MG) followed pseudo-first-order kinetics. The highest photocatalytic
activity of LDH4 ascribed to the oxo-bridged system was explained
by UV–vis DRS and EPR study.The degradation of MG followed
pseudo-first-order kinetics, and the photocatalytic degradation mechanism
was also explained in detail