Presynthesized and In-Situ Generated Tetrazolate Ligand in the Design of Chiral Cadmium Coordination Polymer

Abstract

In contrast to the in-situ generated 5-(4-pyridyl)­tetrazolate (4-ptz) ligand, the use of presynthesized 4-ptz led to the formation of a chiral cadmium coordination polymer with a rare μ₅-bridging mode of the tetrazolate ligand. This type of tuning in the design of chiral coordination polymers is reported for the first time