Surfactant-Mediated One-Pot Method To Prepare Pd–CeO<sub>2</sub> Colloidal Assembled Spheres and Their Enhanced Catalytic
Performance for CO Oxidation
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Abstract
A simple,
one-pot method to fabricate ordered, monodispersed Pd–CeO<sub>2</sub> colloidal assembled spheres (CASs) was developed using the
surfactant-mediated solvothermal approach, which involves a tunable
self-assembled process by carefully controlling different chemical
reactions. The evolution process and formation mechanism of the CASs
were thoroughly investigated by time-controlled and component-controlled
experiments. For CO oxidation, this CAS nanocatalyst exhibited much
higher catalytic activity and thermal stability than Pd/CeO<sub>2</sub> prepared by an impregnation method, and its complete CO conversion
temperature is ∼120 °C. The enhanced catalytic performance
for CO oxidation could be attributed to the synergistic effect of
highly dispersed PdO species and Pd<sup>2+</sup> ions incorporated
into the CeO<sub>2</sub> lattice. For this CAS catalyst, each sphere
can be viewed as a single reactor, and its catalytic performance can
be further improved after being supported on alumina, which is obviously
higher than results previously reported. Furthermore, this method
was used to successfully prepare M–CeO<sub>2</sub> CASs (M
= Pt, Cu, Mn, Co), showing further that this is a new and ideal approach
for fabricating active and stable ceria-based materials