Phase transitions in a metal–organic coordination polymer: [Zn<sub>2</sub>(C<sub>8</sub>H<sub>4</sub>O<sub>4</sub>)<sub>2</sub>(C<sub>6</sub>H<sub>12</sub>N<sub>2</sub>)] with guest molecules. Thermal effects and molecular mobility

Abstract

<p>Thermal effects of a series of [Zn<sub>2</sub>(C<sub>8</sub>H<sub>4</sub>O<sub>4</sub>)<sub>2</sub>(C<sub>6</sub>H<sub>12</sub>N<sub>2</sub>)] porous compound with the guest molecules located in the pores were studied using differential scanning calorimetry combined with solid-state <sup>1</sup>H nuclear magnetic resonance spectroscopy. The intercalation of the molecules was shown to produce various thermal anomalies and phase transitions, which were characterized and analyzed.</p

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