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一种基于丁香酚的多官能团不饱和单体、制备方法及其应用
Authors
代金月
刘小青
+5 more
朱锦
沈潇斌
王静刚
腾娜
马松琪
Publication date
20 April 2016
Publisher
Abstract
本发明公开了一种基于丁香酚的多官能团不饱和单体、制备方法及其应用,丁香酚与巯基羧酸在紫外灯和催化剂共同作用下,发生点击化学反应,得到丁香酚-巯基羧酸化合物;丁香酚-巯基羧酸化合物与烯烃环氧化合物发生环氧开环反应,得到基于丁香酚的多官能团不饱和单体。本发明提供的基于丁香酚的多官能团不饱和单体结构中可引入较多活性官能团,有助于提高聚合物的交联度,提高聚合物的玻璃化转变温度和热变形温度;单体结构中含有的丁香酚骨架赋予聚合物良好的力学性能和热学性能,大量柔性键有助于提高聚合物的强度、模量、抗蠕变、柔韧性等性能
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Institutional Repository of Ningbo Institute of Material Technology & Engineering, CAS
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oai:ir.nimte.ac.cn/:174433/156...
Last time updated on 22/01/2018
Institutional Repository of Ningbo Institute of Material Technology & Engineering, CAS
See this paper in CORE
Go to the repository landing page
Download from data provider
oai:ir.nimte.ac.cn/:174433/262...
Last time updated on 04/12/2021