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一种富氮ZMOF类型金属有机骨架多孔材料的制备方法
Authors
孔春龙
曹鲁杰
闫秋菊
陈亮
Publication date
13 February 2013
Publisher
Abstract
本发明提供了一种新型富氮ZMOF类型金属有机骨架多孔材料的制备方法,该方法采用富氮唑类化合物作为反应用配体,与含有Zn2+的可溶锌盐在有机溶剂中发生溶剂热反应,得到富氮ZMOF类型金属有机骨架多孔材料,然后洗涤、抽真空以及高温活化,使有机溶剂从该富氮ZMOF类型金属有机骨架多孔材料中脱除。采用该方法制备得到的富氮ZMOF类型金属有机骨架多孔材料具有规则的晶体结构与均匀的孔径分布,较好的物理化学稳定性,以及优良的CO2选择吸附能力,因此在CO2捕获分离技术领域、有机分子的分离等技术领域具有很好的应用前景
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Last time updated on 22/01/2018