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Wide-field imaging of single nanoparticle extinction with sub-nm2 sensitivity

Abstract

We report a highly sensitive wide-�eld imaging technique for quantitative measurement of the optical extinction cross-section �ext of single nanoparticles. The technique is simple and high-speed, and enables simultaneous acquisition of hundreds of nanoparticles for statistical analysis. Using rapid referencing, fast acquisition, and a deconvolution analysis, a shot-noise limited sensitivity down to 0.4nm2 is achieved. Measurements on a set of individual gold nanoparticles of 5nm diameter using this method yield �ext = (10:0 � 3:1)nm2, consistent with theoretical expectations, and well above the background uctuations of 0.9nm2

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