In hierarchical structure formation scenarios, galaxies accrete along high density filaments. Superclusters represent the largest density enhancements in the cosmic web with scales of 100 to 200 Mpc. As they represent the largest components of LSS, they are very powerful tools to constrain cosmological models. Since they also offer a wide range of density, from infalling group to high density cluster core, they are also the perfect laboratory to study the influence of environment on galaxy evolution. I will present a newly discovered large scale structure at z=0.65 in the UKIDSS UDS field. Although statistically predicted, the presence of such structure in UKIDSS, one of the most extensively covered and studied extragalactic field, remains a serendipity. Our follow-up confirmed more than 15 group members including at least three galaxy clusters with M200~10^14Msol . Deep spectroscopy of the quiescent core galaxies reveals that the most massive structure knots are at very different formation stage with a range of red sequence properties. Statistics allow us to map formation age across the structure denser knots and identify where quenching is most probably occurring across the LSS. Spectral diagnostics analysis also reveals an interesting population of transition galaxies we suspect are transforming from star-forming to quiescent galaxies