In the present work we report dating procedure of these shells by using the electron paramagnetic resonance. The first step of the analysis was the definition of the optimal procedure for sample preparation. At this aim the analysis of the sample composition was carried out by X-ray fluorescence (XRF) measurements and an accurate analysis was study on the effect of the chemical etching with varying typology and concentration of acid to be used for removing the external layer of shells which are affected by alpha particles