2005-2006 > Academic research: refereed > Publication in refereed journalVersion of RecordPublishe

Hu, JY

Li, Y

Wang, JM

Zhu, CC

PolyU Institutional Repository

? 26 ?? 4?2005 ? 8??　?　?　?Journal of Textile ResearchVol.26 , No.4Aug., 2005?????????????????????王进美1, 2 ,朱长纯1 ,李毅3 ,胡军岩3(1.?????? ????????? ,?? ??　710049;2.???????? ??????? ,?? ??　710048;3.?????? ?????? ,??)?　?　????????????? ,?? Mini-tab DOE??????????? ,???????????????????????? 、????????? 、??????? 、?????? 4 ???????????????????? ,???????????????。???????????????? , ??????????????????????? ,?????????????????? 16 Ψ, ?????????????。??????????????????????? , SE ?? 48 dB。???????????? 、?? 、??? 、????????????????? 。???　????;??????;????;????;?????????:TS 157　　　?????:A　　　????:0253-9721(2005)04-0010-04Coating for fabrics with nano tube-PANIs and the properties ofconducting and shielding microwaveWANG Jin-mei1, 2 , ZHU Chang-chun1 , LI Yi3 , HU Jun-yan3(1.School of Electronics and Information Engineering , Xi' an Jiaotong University , Xi' an , Shanxi　710049 , China;2.Faculty of Textile and Material , Xi' an University of Engineering Science &Technology , Xi' an , Shanxi　710048 , China;3.Institute of Textile and Clothing , The Hong Kong Polytechnic University , Hong Kong , China)Abstract　The perfect coating agents were prepared by use of the Mini-tab DOE anlysis experiment with the ratio of nano-tuberPANIs and the hydrochloric PANIs , the dosage of CNT adulterant , the dosage of bonds and the dosage to fabric.The four factoreswere analyszed by testing the surface resistant of the coating fabric.The lowest surface resistance of coating fabric is 16 Ψ, thehighest SE(shielding effectiveness of microwave)is 48 dB , according to a series of coating technique experiments on single factor ,the dosage of agent.So the conductivity and SE of the fabric was improved greatly , the techniques have important applications indevelopment of the anti-electromagnetic wave , conducting electricity , anti-electrostatics , electronic warm fabric or costume.Key words　CNTs;nano tube PANIs;coating treatment;conducting fabric;anti-electromagnetic wave????:国家自然科学基金资助项目(60036010);陕西省教育厅产业化培育项目(02JC14);香港技术创新基金项目(K.14.37.ZP10)。????:王进美(1964-), 男 ,副教授 ,在读博士。研究领域包括纺织功能材料与纳米技术 、特种动物纤维加工等。　　????????????? ,??????????? 、????????????????? ,???????????????[ 1 ～ 3] 。????????????????????? ,????????? 。????????????????? ,???? 、???????? 。Vincent ??????????????????? 、???? 、??????????????? 、???????[ 4] 。Yang C Y ????????????(DBSA)????????? ,????????????????[ 5] 。???????????????? ,????????????“????”????? ,??????????????? ,?????????????。????????????????????。?? ,?????????????????????。????????? 、??????????? ,???????????????? 。?????? ,????????????????????????????? ,??????????????????? ,????????????????? 。???????????-??????? ,??????????? 、?????? 、????? 、??????????? Mini-tab ?DOI :10.13475/j.fzxb.2005.04.004????? ,????????? 、??????? ,?????????? 、??????????? ,??????????。1　????1.1　?????1.1.1　纳米管状聚苯胺　?????? ,????????? ,??? 3 ～ 20 nm ,???30 ～ 40 nm ,????。1.1.2　普通盐酸掺杂聚苯胺　?????? ,????????? ,????。1.1.3　多壁碳纳米管(MWCNT)　???? ,???????????????????? ,???2 ～ 30 nm ,??? 5 ～ 60 nm ,??????????????????? 。1.1.4　聚丙烯酸酯粘合剂 DICRYLAN GF　? CIBA????????。1.1.5　整理材料的配置　???????。1.1.6　实验仪器　???????? 、???? ,??????? 。1.2　Mini-tab DOE?????????????????????????? ,???????????? ,?? Mini-tab DOE????????????????? 。????????????????????????? ,??CNT???????????????????????????? 1??? ,?? 3??????????? 、????? 、??????(o.w.f , %),?????? 、? 、? 3????? ,???????????????????? 、????????? 、??????? ,???????????? ,??????????????? 。??????????????????? ,???????? ,????(20 ℃, 65%)?? 48 h。??????????? ,????????????????? 。1.3　??????????????????? ,?????????????。?????????????????? ,?????????????? 、?????????????。?????????????? ,????????:????※???????※??※??※??※??※?? 、????? 。1.4　??????1.4.1　织物表面比电阻　??? 200 g? 2?????? ,?????? L(cm),??????????? ,???????? W(cm),?? SUNWA YX-960TR??????? R ,????????????? ρ[ 6] , ρ=RL W。ρ??????????????? 1 cm ????(Ψ)。1.4.2　织物微波屏蔽效能 SE 　???????HELETT PACKKATRD Agilent S-Parameter NETWORKAnalyzer 8720ES????? ,????????????????2 250 ～ 2 650MHz[ 7] 。SE =20 ×lg|E0 E1|=20 ×lg|H0 H1|=10 ×lg(W0 W1)　(dB)?? , E0 , H0 ,W0 ? E1 , H1 ,W1 ???????? 、?(?????)??? 、?? 、??? 。2　?????2.1　????? DOE??????Mini-tab????????? ,??????????????????? 1??。?????????????????????????????。? 1　Mini-tab DOE????????????????? ???????????? g???GF g?????? %????? Ψ1 1:0 0.000 0.50 1.0 84.42 0∶1 0.000 0.50 2.0 21503 1∶0 0.050 0.50 2.0 16.44 0∶1 0.050 0.50 1.0 1735 1∶0 0.000 1.00 2.0 1516 0∶1 0.000 1.00 1.0 10307 1∶0 0.050 1.00 1.0 46.88 0∶1 0.050 1.00 2.0 10809 0.5∶0.5 0.025 0.75 1.5 42.410 0.5∶0.5 0.025 0.75 1.5 36.511 0.5∶0.5 0.025 0.75 1.5 55.212 0.5∶0.5 0.025 0.75 1.5 49.2? 1　Mini-tab?????112005?　?4? ???? 【　】? 2　???????　　?? Mini-tab ????????? ,?????? 、???????1 ,2?? 。?????? ,???????????? ????????? 、?????? 、?????? GF ?????????4??? ,????????????????????:????????????? ,????????????? ,?????????? 。2.1.1　聚苯胺材料对织物导电性的影响　? 1? ,?????????????????????? ,???????? F ????? 180 ,????????? 。?? ,??????????????????。????????????????????????????????????????? ,?? 8???? ,?? 1 ,3 , 5 , 7?????????????? ,??????????? 74.65 Ψ,???? 16.4 Ψ,?? 2 ,4 , 6 ,8??????????????? ,?????????1 108.25 Ψ,????173 Ψ。??????????????? ,???????????????? 10%,????????????? ,?????????????????? ,????????。2.1.2　掺杂剂 CNT 用量对表面比电阻的影响　????3? 5 、2? 8??????? ,??????????? ,??????????? ,?????????? 5%?????????? ,????????????? 200%?? ,?????????????????? ,????????????????? ,????????。?????????????????????????????。?? 1 ,2??? ,??? CNT ??????????? ,???????????????? ,???????????????????。2.1.3　粘合剂用量对表面比电阻的影响　????????????????????????????? 。?????????????? ,???????????? ,?????????????? ,?????????????? 。?????????????? ,?????????? ,???????????????????? 。?1 ,2????????? ,???????????????? 。?? ,??????????????? ,?????????????。2.1.4　整理剂用量对表面比电阻的影响　??????????????????????????????????????????? 。????????????? 3 、7???? 2 、6????????? ,????????????? 200%? ,???????? 30%,??????????????? 200%? ,????????????? 50%。??????????????????。?? DOE??????? ,???????????:???????? 30%,????? 6%,??????? 30%,????? 34%。2.2　??????????2.2.1　整理剂用量对表面比电阻的影响　???????????????????????? ,?????????????????。???????????????? 5? ,??????????? ,?????? ,???? 3 ?? 。?? 3??? ,?????????? ,????????????????? ,? 40%～ 60%??? ,???????????? 。???????[ 8] ,????? 40%? ,??????????????????????? ,???????? ,?????????????????? ,?????????????????? ,???????? ,?????????????????????????1 ～ 2???? ,??DOE????????? 。2.2.2　整理剂用量对微波屏蔽效应的影响　? 4???????????????????。???????2 250 ～ 2 650 MHz??????????????? 。???? ,?????????????????????????? ,??????? ,????????。???????-??????????????????????????????????????????? ,?????? 60%? ,????? SE ?? 48 dB ,????????????? 。???????????12【　】 ???? 2005?　? 4?? 3　????????????????????????????????? ,????????????????。? 4　???????????????????????????? ,? AATCC ???? 20? ,?????????????? ,????????? 5%。?? ,??????????????。3　?　?1)????????????? ,?????　　　???????????????????? ,????????????????????????????????? 。2)?????????????????????? 、??????????? ,?? DOE?????? ,???????? 、???????????。???????????????????????? ,?? 2?????????。3)????????????????????? ,????????? ,?????????????????????????????? 。?????????????? ,??????????16 Ψ,?????????? 48 dB。????:[ 1 ] 　Mahito Atobe , Naki Chowdhury , Toshio Fuchigami , et al.Preparationof conducting polyani line colloids under ultrasonication [ J ] .Ultrasonics Sonochem ,2003 ,(10):77-80.[ 2 ] 　Jeevananda T , Siddaramaiah.Synthesis and characterization ofethylene vinyl-acetate polyaniline blends prepared by emulsionpolymeri zation technique[ J] .Polym Engineering and Sci , 2003 , 43(5):1138-1141.[ 3 ] 　??? ,???.?????????[ M] .??:??????? ,2001.63-77.　[ 4 ] 　Vincent B ,Waterson J.Synthesis and characterization of conductingpoly(aniline-co-o-aminophenethyl alcohol)s[ J] .J Chem Soc ChemCommun , 1990, 16:683-687.[ 5 ] 　Yang C Y , Smith P , Heeger A J , et al.Template-free synthesizedmicrotubules of conducting polymers[ J] .Polymer , 1994, 36:1142-1146.[ 6 ] 　??? ,???.??????????????[ M] .??:????????? , 1995.320-321.[ 7 ] 　???.????????????????????[ J] .???????? , 2002 , 6:32-26.[ 8 ] 　Su Ching Iuan , Chern Jin Tsair.Effect of stainless steel-containingfabrics on electromagnetic shielding effectiveness[ J] .Textile ResearchJournal , 2004 , 74(1):51-55.[ 9 ] 　?? ,??? ,???.???????????????????[ J] .???? , 2003 ,24(3):61-63.132005?　?4? ???? 【　】

Coating for fabrics with nano tube-panis and the properties of conducting and shielding microwave

Abstract

Similar works

Full text

Available Versions

PolyU Institutional Repository