Screen-printed platinum electrodes for the detection of cupric and ferric ions in high chloride backgrounds

Abstract

Screen-printed platinum electrodes developed for use in corrosion monitoring applications have been used to detect cupric and ferric ions both individually and as mixtures in a background of 3.5% by weight sodium chloride and in the presence of dissolved oxygen. In single species detection linear responses for the Fe3+/Fe2+ couple were observed over the concentration range 0.3 to 100mM. By contrast, the small size of the working electrode caused a current limiting response for cupric ions over the same concentration range. In mixtures of these ions, the sensors show good differentiation and are able to separate the individual metal ion responses