Duan-Lukin-Cirac-Zoller (DLCZ) quantum repeater protocol, which was proposed
to realize long distance quantum communication, requires usage of quantum
memories. Atomic ensembles interacting with optical beams based on off-resonant
Raman scattering serve as convenient on-demand quantum memories. Here, a
complete free space, three-dimensional theory of the associated read and write
process for this quantum memory is worked out with the aim of understanding
intrinsic retrieval efficiency. We develop a formalism to calculate the
transverse mode structure for the signal and the idler photons and use the
formalism to study the intrinsic retrieval efficiency under various
configurations. The effects of atomic density fluctuations and atomic motion
are incorporated by numerically simulating this system for a range of realistic
experimental parameters. We obtain results that describe the variation in the
intrinsic retrieval efficiency as a function of the memory storage time for
skewed beam configuration at a finite temperature, which provides valuable
information for optimization of the retrieval efficiency in experiments.Comment: 16 pages, 12 figure