A description of a method of measurement of atmospheric extinction and of ozone profiles by use of the backscatter signal from a monostatic lidar is given. The central feature of the procedure involves a measurement of the ratio of the Raman backscatter returns of both the oxygen and nitrogen atmospheric content. Because the ratio of the number density of both species is known to high accuracy, the measurement itself becomes a measure of the ratio of two transmissions to altitude along with a ratio of the two system constants. The calibration measurement for determining the value of the ratio of the two system constants or electro-optical conversion constants is accomplished by a lidar measurement of identical atmospheric targets while at the same time interchanging the two optical filters in the two optical channels of the receiver. More details of the procedure are discussed. Factoring this calibrated value into the measured O2/N2 profile ratio provides a measured value of the ratio of the two transmissions. Or equivalently, it provides a measurement of the difference of the two extinction coefficients at the O2 and N2 Raman wavelengths as a function of the height