CORE
🇺🇦
make metadata, not war
Services
Services overview
Explore all CORE services
Access to raw data
API
Dataset
FastSync
Content discovery
Recommender
Discovery
OAI identifiers
OAI Resolver
Managing content
Dashboard
Bespoke contracts
Consultancy services
Support us
Support us
Membership
Sponsorship
Community governance
Advisory Board
Board of supporters
Research network
About
About us
Our mission
Team
Blog
FAQs
Contact us
Intramolecular hydrogen transfer reactions of thiyl radicals from glutathione: formation of carbon-centered radical at Glu, Cys and Gly
Authors
Akhlaq M. S.
Christian Schöneich
+49 more
Davies M. J.
Fessenden R. W.
Fossey J.
Fujii J.
Fung Y. M.
Gandini A.
Gilbert H. F.
Grierson L.
Hofstetter D.
Huston P.
Ikehata K.
Karoui H.
Konya K. G.
Linetsky M.
Moger G.
Mozziconacci O.
Mozziconacci O.
Mozziconacci O.
Mozziconacci O.
Mozziconacci O.
Mozziconacci O.
Naumov S.
Nauser T.
Nauser T.
Nauser T.
Niki E.
Oakley A.
Olivier Mozziconacci
Osburn S.
Pogocki D.
Raffy Q.
Rauk A.
Rauk A.
Rauk A.
Reid D. L.
Roberts B. P.
Ross D.
Schöneich C.
Schöneich C.
Schöneich C.
Skelton J.
Tew K. D.
Todd D. Williams
Viskolcz B.
Volman D. H.
Von Sonntag C.
Younis I. R.
Zhao R.
Zhao R.
Publication date
17 September 2012
Publisher
'American Chemical Society (ACS)'
Doi
Cite
View
on
PubMed
Abstract
This document is the Accepted Manuscript version of a Published Work that appeared in final form in Chemical Research in Toxicology, copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see http://pubs.acs.org/doi/abs/10.1021/tx3000494Glutathione thiyl radicals (GS•) were generated in H2O and D2O by either exposure of GSH to AAPH#, photoirradiation of GSH in the presence of acetone, or photoirradiation of GSSG. Detailed interpretation of the fragmentation pathways of deuterated GSH and GSH-derivatives during mass spectrometry analysis allowed us to demonstrate that reversible intramolecular H-atom transfer reactions between GS• and C-H bonds at Cys[αC], Cys[βC], and Gly[αC] are possible
Similar works
Full text
Open in the Core reader
Download PDF
Available Versions
Crossref
See this paper in CORE
Go to the repository landing page
Download from data provider
info:doi/10.1021%2Ftx3000494
Last time updated on 04/12/2019
KU ScholarWorks
See this paper in CORE
Go to the repository landing page
Download from data provider
oai:kuscholarworks.ku.edu:1808...
Last time updated on 09/07/2019