Vector vortex beams are structured states of light that are non-separable in
their polarisation and spatial mode, they are eigenmodes of free-space and many
fibre systems, and have the capacity to be used as a modal basis for both
classical and quantum communication. Here we outline recent progress in our
understanding of these modes, from their creation to their characterization and
detection. We then use these tools to study the propagation behaviour of such
modes in free-space and optical fibre and show that modal cross-talk results in
a decay of vector states into separable scalar modes, with a concomitant loss
of information. We present a comparison between probabilistic and deterministic
detection schemes showing that the former, while ubiquitous, negates the very
benefit of increased dimensionality in quantum communication while reducing
signal in classical communication links. This work provides a useful
introduction to the field as well as presenting new findings and perspectives
to advance it further
