The diagnosis of historical building materials is quite relevant for a complete knowledge of
construction rules as well as during focused restoration actions. In particular, the identification of
natural building stones employed in the manufacture of historical monuments is the first step to
understand causes of weathering processes, to choose the most appropriate conservation and/or
protection treatments and to select the materials to employ in replacements during the restoration
works. In some cases, the high architectural value of the investigated elements prevents any
sampling, needing the application of portable instruments for the non-destructive in situ analysis of
building stone materials.
However, the routinely application of portable methodologies to diagnosis and conservation
actions imply the standardization of testing procedures and creation of appropriate reference
database to carry out reliable comparisons between building and (probable) quarry materials.
For the aforementioned, in this contribute we present an experimental study performed by using
a portable X-ray device, namely the Bruker Tracer IV instrument on reference basalt natural stones
sampled in some of the Sicilian quarries and used in the local historical architecture to standardize
and subsequently for in situ analysis of building materials. Thus, non-destructive measurements
have been carried out on the basalt columns of the St. Mary Cathedral in Randazzo (Sicily) - a
relevant historical building founded in the 12th century, but completely renovated during the
Renaissance period (Cultrone et a., 2001; Sanfilippo, 2008) - in order to test the method for stone
classification and identification of quarries.
This approach has allowed to identify raw materials employed in the manufacture of the
columns of the Cathedral, supporting the creation of a database of Etna lavas quarried over the
time for building manufacture and the standardization of the instrument for future in situ
applications