CORE
🇺🇦
make metadata, not war
Services
Services overview
Explore all CORE services
Access to raw data
API
Dataset
FastSync
Content discovery
Recommender
Discovery
OAI identifiers
OAI Resolver
Managing content
Dashboard
Bespoke contracts
Consultancy services
Support us
Support us
Membership
Sponsorship
Community governance
Advisory Board
Board of supporters
Research network
About
About us
Our mission
Team
Blog
FAQs
Contact us
research
Thorium nanochemistry: The solution structure of the Th(iv)-hydroxo pentamer
Authors
M. Fuss
J. Rothe
B. Schimmelpfennig
C. Walther
Publication date
1 January 2012
Publisher
Cambridge : Royal Society of Chemistry
Doi
Cite
Abstract
Tetravalent thorium exhibits a strong tendency towards hydrolysis and subsequent polymerization. Polymeric species play a crucial role in understanding thorium solution chemistry, since their presence causes apparent solubility several orders of magnitude higher than predicted by thermodynamic data bases. Although electrospray mass spectrometry (ESI MS) identifies Th(iv) dimers and pentamers unequivocally as dominant species close to the solubility limit, the molecular structure of Th 5(OH) y polymers was hitherto unknown. In the present study, X-ray absorption fine structure (XAFS) spectroscopy, high energy X-ray scattering (HEXS) measurements, and quantum chemical calculations are combined to solve the pentamer structure. The most favourable structure is represented by two Th(iv) dimers linked by a central Th(iv) cation through hydroxide bridges. © 2012 The Royal Society of Chemistry
Similar works
Full text
Open in the Core reader
Download PDF
Available Versions
Institutionelles Repositorium der Leibniz Universität Hannover
See this paper in CORE
Go to the repository landing page
Download from data provider
oai:www.repo.uni-hannover.de:1...
Last time updated on 21/11/2017