Resonant X-ray emission spectroscopy reveals d–d ligand-field states involved in the self-assembly of a square-planar platinum complex

Adamovich; Arena; Bailey; Bergmann; Carlo Lamberti; Claudio Garino; Dedieu; Dickinson; Ditchfield; Erik Gallo; Fuentealba; Gauthier; Gel′mukhanov; Glatzel; Glatzel; Glatzel; Goshe; Jimenez-Mier; Kotani; Krause-Heuer; Krogmann; Lippard; Lowe; Luca Salassa; McMillin; Nikolay Smolentsev; Peter J. Sadler; Pieter Glatzel; Ratilla; Roberto Gobetto; Schwarz; Smolentsev; Tao; Yam; Yam; Yip; Yu

research

Resonant X-ray emission spectroscopy reveals d–d ligand-field states involved in the self-assembly of a square-planar platinum complex

Authors: Adamovich
Arena
Bailey
Bergmann
Carlo Lamberti
Claudio Garino
Dedieu
Dickinson
Ditchfield
Erik Gallo
Fuentealba
Gauthier
Gel′mukhanov
Glatzel
Glatzel
Glatzel
Goshe
Jimenez-Mier
Kotani
Krause-Heuer
Krogmann
Lippard
Lowe
Luca Salassa
McMillin
Nikolay Smolentsev
Peter J. Sadler
Pieter Glatzel
Ratilla
Roberto Gobetto
Schwarz
Smolentsev
Tao
Yam
Yam
Yip
Yu
Publication date: 1 January 2012
Publisher: 'Royal Society of Chemistry (RSC)'
Doi

Abstract

Resonant X-ray Emission Spectroscopy (RXES) is used to characterize the ligand field states of the prototypic self-assembled square-planar complex, [Pt(tpy)Cl]Cl (tpy=2,2′:6′,2′′-terpyridine), and determine the effect of weak metal-metal and π-π interactions on their energy. © 2012 the Owner Societies