Very High Surface Area Mesoporous Thin Films of SrTiO3_{3} Grown by Pulsed Laser Deposition and Application to Efficient Photoelectrochemical Water Splitting

Abstract

Very high surface area, self-assembled, highly crystalline mesoporous SrTiO3_{3} (STO) thin films were developed for photoelectrochemical water splitting. Much improved performance of these mesoporous films compared to planar STO thin films and any other form of STO such as single crystal samples and nanostructures was demonstrated. The high performance resulted from very large surface area films and optimization of carrier concentration.We gratefully acknowledge the support from the Cambridge Commonwealth Trust, ERC adg grant (247276) NOVOX and UKIERI grant (IND/CONT/E/12-13/813). The TEM work at Texas A&M University is funded by the US National Science Foundation (DMR-1401266)

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