Generation of strength in a drying film: How fracture toughness depends on dispersion properties

Abstract

The fracture toughness of colloidal films is measured by characterizing cracks which form during directional drying. Images from a confocal microscope are processed to measure the crack width as a function of distance from the crack tip. Applying theory for thin elastic films the fracture toughness is extracted. It is found that the fracture toughness scales with the particle size to the −0.8 power and that the critical energy release rate scales with the particle size to the −1.3 power. In addition, the fracture toughness is found to increase at lower evaporation rates, but the film thickness does not have a significant effect.We thank Professor Bill Clegg for helpful discussions, and Martin Lippert for help with matlab, as well as the Ernest-Solvay-Stiftung and Studienstiftung des deutschen Volkes for financial support of the research visit of N.B.-B. from Karlsruhe Institute of Technology (KIT) to the University of Cambridge