In situSR-PXD experiments revealed a new reaction mechanism of amide–hydride anionic exchange for the K–Mg–N–H system

Balmes, O.

Bergemann, N.

Cao, H.

Dornheim, M.

Enzo, S.

Garroni, S.

Girella, A.

Haase, D.

Klassen, T.

Le, T.T.

Marini, A.

Masolo, E.

Milanese, C.

Mulas, G.

Pistidda, C.

Santoru, A.

Taube, K.

Valentoni, A.

Physical Chemistry Chemical Physics

English

New insights into the reaction pathways of different potassium/magnesium amide-hydride based systems are discussed. In situ SR-PXD experiments were for the first time performed in order to reveal the evolution of the phases connected with the hydrogen releasing processes. Evidence of a new K-N-H intermediate is shown and discussed with particular focus on structural modification. Based on these results, a new reaction mechanism of amide-hydride anionic exchange is proposed

MILANESE, CHIARA

GIRELLA, ALESSANDRO

MARINI, AMEDEO

Le, T. T.

Archivio Istituzionale della Ricerca - Università degli Studi di Pavia

A new potassium-based intermediate and its role in the desorption properties of the K-Mg-N-H system

Santoru, A

Garroni, S

Pistidda, C

Milanese, C

Girella, A

Marini, A

Masolo, E

Valentoni, A

Bergemann, N

Le, T T

Cao, H

Haase, Dörthe

Balmes, Olivier

Taube, K

Mulas, G

Enzo, S

Klassen, T

Dornheim, M

Lund University Publications

A new potassium-based intermediate and its role in the desorption properties of the K-Mg-N-H system.

Open Access Repository

A new potassium-based intermediate and its role in the desorption properties of the K–Mg–N–H system

In situSR-PXD experiments revealed a new reaction mechanism of amide–hydride anionic exchange for the K–Mg–N–H system.</p

A new potassium-based intermediate and its role in the desorption properties of the K–Mg–N–H system

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Archivio Istituzionale della Ricerca - Università degli Studi di Pavia

Lund University Publications

Open Access Repository

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