We introduce the discording power of a unitary transformation, which assesses
its capability to produce quantum discord, and analyze in detail the generation
of discord by relevant classes of two-qubit gates. Our measure is based on the
Cartan decomposition of two-qubit unitaries and on evaluating the maximum
discord achievable by a unitary upon acting on classical-classical states at
fixed purity. We found that there exist gates which are perfect discorders for
any value of purity, and that they belong to a class of operators that includes
the $\sqrt{{SWAP}}. Other gates, even those universal for quantum computation,
do not posses the same property: the CNOT, for example, is a perfect discorder
only for states with low or unit purity, but not for intermediate values. The
discording power of a two-qubit unitary also provides a generalization of the
corresponding measure defined for entanglement to any value of the purity.Comment: accepted for publication in Physical Review Letter