Synthesis and Reactivity of Tricarbonyl(1-ethoxy-carbonyl-2-methylpentadienyl)iron(1+) Cation

Abstract

The title cation was prepared in two steps from the known (ethyl 3-methyl-6-oxo-2,4-hexadienoate)Fe(CO)3. Reation of the cation with NaBH3CN, methyl cuprate, phthalimide, water, PPh3, or malonate anions gave predominantly the products from nucleophilic attack at the C5 pentadienyl carbon